Exogenous-oxidant-free electrochemical oxidative C–H phosphonylation with hydrogen evolution
Chemical Communications2019Vol. 55(29), pp. 4230–4233
Citations Over TimeTop 10% of 2019 papers
Yong Yuan, Jin Li Qiao, Yangmin Cao, Jingmei Tang, Mengqin Wang, Guojuan Ke, Yichen Lu, Xue Liu, Aiwen Lei
Abstract
We herein report a versatile and environmentally friendly electrochemical oxidative C-H phosphonylation protocol. This protocol features a broad substrate scope; not only C(sp2)-H phosphonylation, but also C(sp3)-H phosphonylation is tolerated well under exogenous-oxidant-free and metal catalyst-free electrochemical oxidation conditions.
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