A scalable electrochemical dehydrogenative cross-coupling of P(O)H compounds with RSH/ROH
Chemical Communications2019Vol. 55(34), pp. 4981–4984
Citations Over TimeTop 10% of 2019 papers
Abstract
A practical, scalable electrochemical dehydrogenative cross-coupling of P(O)H compounds with thiols, phenols and alcohols in both an undivided cell and a continuous-flow setup is disclosed. Its broad substrate scope (>50 examples), good functional-group tolerance and scalability (>10 g) show potential for practical synthesis. A preliminary mechanistic study suggests that the phosphorus radicals are involved in the catalytic cycle.
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