Fused rings with N-oxide and –NH2: good combination for high density and low sensitivity energetic materials
Chemical Communications2019Vol. 55(61), pp. 8979–8982
Citations Over TimeTop 10% of 2019 papers
Abstract
Oxidation reactions of 3,6-diamino-1,2,4-triazolo[4,3-b][1,2,4,5]tetrazine give four N-oxide compounds. Because of the presence of an amino group and the N-oxide moiety, these compounds are extensively hydrogen bonded. Resulting from π-π stacking interactions between the fused rings, compounds 1-3 are impact and friction insensitive, are thermally stable and have good density.
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