Ag-Catalyzed ring-opening of tertiary cycloalkanols for C–H functionalization of cyclic aldimines
Chemical Communications2021Vol. 57(12), pp. 1506–1509
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Jingjing Wang, Xue Liu, Ziyan Wu, Feng Li, Mingliang Zhang, Yiman Mi, Junhao Wei, Yao Zhou, Lantao Liu
Abstract
We firstly describe a silver-catalyzed direct C-H functionalization of cyclic aldimines with cyclopropanols and cyclobutanols via a radical-mediated C-C bond cleavage strategy. The desired products were generated in decent yields with wide substrate scope under mild reaction conditions. In addition, a gram-scale reaction and synthetic transformation of the product were performed.
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