Metal–organic frameworks as catalytic selectivity regulators for organic transformations

Citations Over TimeTop 1% of 2021 papers

Abstract

Selective organic transformations using metal-organic frameworks (MOFs) and MOF-based heterogeneous catalysts have been an intriguing but challenging research topic in both the chemistry and materials communities. Analogous to the reaction specificity achieved in enzyme pockets, MOFs are also powerful platforms for regulating the catalytic selectivity via engineering their catalytic microenvironments, such as metal node alternation, ligand functionalization, pore decoration, topology variation and others. In this review, we provide a comprehensive introduction and discussion about the role of MOFs played in regulating and even boosting the size-, shape-, chemo-, regio- and more appealing stereo-selectivity in organic transformations. We hope that it will be instructive for researchers in this field to rationally design, conveniently prepare and elaborately functionalize MOFs or MOF-based composites for the synthesis of high value-added organic chemicals with significantly improved selectivity.

Related Papers

• → Enhanced catalytic activity of Pt/Al2O3 on the CH4 SCR(2011)24 cited
• → Catalytic reduction of N2O with CH4 over FeAlPO-5 catalyst(2008)15 cited
• → Determining influence of catalyst-reductant morphology on two different mechanisms of SCR by MOFs(2021)3 cited
• → Catalytic activity of H3PMo12−XWXO40 and H6P2MO18−XWXO62 heteropolyacid (HPA) catalysis in the direct preparation of dichloropropanol (DCP) from glycerol(2008)9 cited
• → Different Selectivity Systems(2006)