Topochemically synthesized Nb3VS6 as a stable anode for sodium-ion batteries
Chemical Communications2024Vol. 60(73), pp. 10017–10020
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Harshit Pandey, Pallellappa Chithaiah, Savithri Vishwanathan, H. S. S. Ramakrishna Matte, C. N. R. Rao
Abstract
Ternary metal sulfides having layered morphology are considered as potential active materials for various applications. Herein, Nb3VS6 is synthesized topochemically for the first time using a Nb-V-HDA complex having a lamellar structure by employing H2S gas as the sulfidation agent. Nb3VS6, as an anode for SIBs, exhibited a specific capacity of 101.15 mA h g-1 at 0.5 A g-1, along with excellent cycling stability with 100% capacity retention after 2500 cycles.
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