Benign methylformamidinium byproduct induced by cation heterogeneity inhibits local formation of δ-phase perovskites
Energy & Environmental Science2024Vol. 17(23), pp. 9134–9143
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Jihoo Lim, Jaehui Kim, Josh Davies-Jones, Mohsen Danaie, Eun Young Choi, Hongjae Shim, Liang Chen, Jincheol Kim, Judy S. Kim, Philip R. Davies, Jan Seidel, Martin A. Green, Samuel D. Stranks, Sang Il Seok, Jae Sung Yun
Abstract
Methylammonium chloride (MACl) selectively promotes the formation of N -methylformamidinium (MFA + )PbI 3 at grain boundaries (GBs) and as clusters near GBs while suppress the formation of δ-FAPbI 3.
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