Structure Correlation Study of Some Diels–Alder Cycloadducts of Anthracene
Australian Journal of Chemistry2009Vol. 62(5), pp. 419–424
Citations Over Time
Abstract
Crystal structures of some Diels–Alder cycloadducts of anthracene and a variety of dienophiles reveal structural effects consistent with the manifestation of the early stages of the retro Diels–Alder reaction in the ground state structure. The symmetrical cycloadducts 3 and 4 reveal a qualitative relationship between structure and reactivity, whereas the cycloadducts of 9-methoxyanthracene show structural effects suggestive of the early stages of an asynchronous retro Diels–Alder reaction.
Related Papers
- → 9-Anthryldiazomethane in the Synthesis of Anthracene- Containing Polymers(1978)16 cited
- → 1‐Azabenz[a]anthracene and 9‐azabenz[a]anthracene(1985)11 cited
- → Kinetic studies on the mechanism of the nitraminopyridine rearrangement(1982)3 cited
- → Studies in heterocyclics: synthesis of 7-substituted 3-Phenyl-1H-imidazo[l,2-a]benzimidazoles(1981)4 cited
- → The Mechanism and Stereochemistry of Chlorination of Some 2,4-Dichloro-6-methylphenols; X-Ray Crystal Structures of Some Polyhalo Ketones(1994)3 cited