NHC-Based Self-Assembled Monolayers on Solid Gold Substrates
Australian Journal of Chemistry2011Vol. 64(8), pp. 1177–1179
Citations Over TimeTop 17% of 2011 papers
Tobias Weidner, Joe E. Baio, Alexander Mundstock, Christoph Große, Silvia Karthäuser, Clemens Bruhn, Ulrich Siemeling
Abstract
Thin films of 1,3-diethylbenzimidazol-2-ylidene (BIEt) were fabricated from THF solution on solid gold substrates and characterised by high-resolution X-ray photoelectron and near-edge X-ray absorption fine structure spectroscopy. The surface-analytical data are in accord with the formation of self-assembled monolayers of BIEt molecules exhibiting an approximately vertical orientation on the substrate. The crystal structure of (BIEt)(2) was also determined.
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