Analysis of the electron paramagnetic resonance zero-field splitting forFe3+in sapphire
Physical review. B, Condensed matter1987Vol. 36(1), pp. 712–714
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Abstract
The EPR zero-field splitting of ${\mathrm{Fe}}^{3+}$ in a trigonal-symmetry crystal field has been calculated on the basis of the complete matrices for ligand-field spin-orbit coupling of the ${d}^{5}$ configuration with ${C}_{3}$ symmetry. The absorption spectrum and the EPR zero-field-splitting axial parameters D and F, and the cubic parameter a for the ${\mathrm{Fe}}^{3+}$ ion in sapphire have been interpreted uniformly.
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