Role of cationic polarization in humus‐increased soil aggregate stability

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Abstract

It is well known that humus markedly increases soil aggregate stability, but at the same time strongly decreases the flocculation of clay particles in suspension. These seemingly inconsistent observations suggest the need for a deeper understanding of the physical mechanisms that govern clay–humus interactions. In this research, soil samples from an Entisol were used to explore the role of cationic polarization in humus‐increased soil aggregate stability and sodium ( Na + ) and potassium ( K + ) ions were used to characterize weak and strong polarization, respectively. The results showed that strong cationic polarization has a critical role in increased soil aggregate stability in the presence of humus. We concluded that, without cationic polarization, the effects of humus alone on soil aggregate stability were weak in the presence of monovalent metal cations. When we compared the individual contributions of humus and strong cationic polarization, the latter proved much more important than humus in increasing soil aggregate stability. The strongest increase in soil aggregate stability occurred when strong cationic polarization was coupled with humus. The combined analysis of activation energy of soil flocculation in suspension and soil aggregate stability in the presence of humus indicated that humus increased the long‐range electrostatic repulsive force of soil particles, and increased the short‐range attractive force of soil particles. Consequently, humus decreased the flocculation of soil particles in suspension but increased soil aggregate stability; all effects were adjusted by the strength of cationic polarization. Highlights Elucidation of physical mechanisms of cation–surface interactions that determine clay–humus interactions. Cations at the particle surface of the clay–humus complex are strongly polarized. Cationic polarization has a critical role in humus‐increased soil aggregate stability. Without cationic polarization, the effect of humus alone on soil aggregate stability was weak.

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