Chemoselective light‐induced reactivity of β‐enaminones
Photochemistry and Photobiology2023Vol. 100(4), pp. 1068–1077
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Abstract
The irradiation of β-enaminones, generated in situ from cyclic 1,3-diketones and activated alkenes leads to polyheterocyclic skeletons. The photoproduct chemoselectivity depends on the type of cyclic 1,3-diketones employed viz., 2-acetylcyclopentanone and 2-acetylcyclohexanone. The observed chemoselectivity was rationalized based on the Dieckmann-Kon rule.
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