Ethene/Norbornene Copolymerization with (Isodicyclopentadienyl)titanium Complex-MAO Catalyst
Collection of Czechoslovak Chemical Communications2007Vol. 72(5-6), pp. 697–702
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Abstract
Norbornene (NB) homopolymerization and ethene/NB copolymerizations with a silylene-bridged (isodicyclopentadienyl)( tert -butylamido)titanium dichloride-methylalumoxane (MAO) catalyst system were investigated. This catalytic system shows no efficiency towards NB homopolymerization but produces poly(ethene- co -norbornene)s. An increase in the initial NB feed content leads to a loss of copolymerization activity as well as NB copolymer incorporation. The structure of the isodicyclopentadienyl fragment (IsodiCp) has a strong limiting effect on comonomer incorporation possibilities.
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