IONIZATION AND DISSOCIATION OF FORMATE ESTERS BY ELECTRON IMPACT
Canadian Journal of Chemistry1963Vol. 41(8), pp. 2054–2059
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Abstract
The mass spectra of methyl formate-d, ethyl formate-d, and isopropyl formate-d are compared with the mass spectra of the undeuterated compounds. By use of the deuterium labelling and appearance potential studies the dissociation reactions leading to a number of the oxygen-containing ions have been elucidated. The proton affinity of formic acid is estimated to be 157 kcal/mole from the appearance potential of the HC(OH) 2 + ion in the mass spectra of ethyl formate and isopropyl formate.
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