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Photochemical rearrangement of diene endoperoxides
Canadian Journal of Chemistry1970Vol. 48(20), pp. 3265–3268
Citations Over TimeTop 10% of 1970 papers
Abstract
It has been shown that the direct irradiation of cyclic peroxides such as ascaridole, and those derived from cyclohexadiene, 1,3,5,5-tetramethylcyclohexadiene, and levopimaric acid methyl ester rearrange on irradiation. The bisepoxides are obtained, as in the thermal rearrangement, together with, where the structure permits, the ketoepoxide. The reaction can be induced by triplet–triplet energy transfer.
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