Kinetic Studies of the Reaction of Picryl Chloride with Sodium Methoxide in Methanol
Canadian Journal of Chemistry1974Vol. 52(1), pp. 18–24
Abstract
Picryl chloride reacts rapidly with methoxide ion in methanol to form a σ-complex containing methoxide ion attached to the C-3 position of the picryl chloride. Thermodynamic and kinetic parameters characterizing this reaction are presented and compared with corresponding parameters for the analogous reaction of methoxide ion and 2,4,6-trinitroanisole in methanol. Details concerning the much slower formation of the σ-complex containing methoxide ion added to the C-1 position of picryl chloride are also presented.
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