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Nuclear analogs of β-lactam antibiotics. XII. 2-Oxodesthiocephalosporins
Canadian Journal of Chemistry1979Vol. 57(6), pp. 614–625
Citations Over TimeTop 15% of 1979 papers
Abstract
Epoxidation of Δ 2 -1-carbacephems 2 followed by base treatment gave the allylic alcohols 4. Oxidation of 4 gave the 2-keto-Δ 3 -carbacephem 9 which could be reduced to the isomeric allylic alcohol 7. Conversion of these intermediates to a series of biologically active cephalosporin analogs 13g–l and 14 is described.
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