A Key Role of Orbital Interaction in the Main Group Element-containing π-Electron Systems
Chemistry Letters2004Vol. 34(1), pp. 2–7
Citations Over TimeTop 10% of 2004 papers
Abstract
Abstract Various types of main group element-containing π-electron systems have been synthesized using silole, dibenzoborole, or bis-silicon-bridged stilbene as the key building units. In these π-electron systems, the orbital interaction between the main group element moiety and the π-conjugated framework, such as pπ–π* and σ*–π* conjugation, plays a crucial role in determining their characteristic electronic structures and makes them promising materials for applications in organic electronics and optoelectronics.
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