Electronically Tunable Compact Trialkylphosphines: SMAPs-bridged Bicyclic Phosphines
Chemistry Letters2006Vol. 35(3), pp. 294–295
Citations Over TimeTop 12% of 2006 papers
Abstract
Abstract A series of silicon-constrained monodentate trialkylphosphines SMAPs bearing a Si substituent with diverse electronic natures were synthesized. DFT calculations and NMR measurements indicated that these compounds constitute a class of electronically tunable trialkylphosphines. The tunable range of donor power overlaps those of tri(tert-butyl)phosphine and monoalkyldiarylphosphines.
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