Sai P. Shum

Publications by Year

Research Areas

Synthesis and characterization of novel inorganic/organometallic compounds, Organophosphorus compounds synthesis, Organometallic Complex Synthesis and Catalysis, Asymmetric Hydrogenation and Catalysis, Crystallization and Solubility Studies

Most-Cited Works

• → Sterically Congested Phosphite Ligands: Synthesis, crystallographic characterization, and observation of unprecedented eight‐Bond 31P,31P coupling in the 31P‐NMR spectra(1993)70 cited
• → The Thermal Reaction of Sterically Hindered Nitroxyl Radicals with Allylic and Benzylic Substrates: Experimental and Computational Evidence for Divergent Mechanisms(2002)58 cited
• → Novel sterically congested chiral tripodal phosphite ligands: catalytic asymmetric hydrosilylation of ketones with a Rh(I)–TRISPHOS catalyst(1998)30 cited
• → Atomic Proximity Due to Molecular Congestion: Rational Design of Bis(phosphite) Ligands by Restriction of Molecular Motion1(1996)30 cited
• → Ferrocene Bis(phosphonite)s: Synthesis and Characterization of a Novel Class of Sterically Congested Ligands1(2001)21 cited
• → Steric Consequences on the Conformation of Medium-Sized Rings: Solution NMR, Solid-State Crystallographic, ab Initio Molecular Orbital Calculations, and Molecular Mechanics Studies on Substituted Eight-Membered Organosilicon Ring Systems1(1997)19 cited
• → The Conformation of Medium‐Sized Organosilicon Heterocycles: First evidence for the existence of a boat‐boat conformation in a 12H‐dibenzo[d,g][1,3,2]dioxasilocin(1993)15 cited
• → Sterically Congested Tripodal Phosphites: Conformational Analysis, Solid-State Polymorphism, Metal Complexation, and Application to the Asymmetric Hydrosilation of Ketones1(2003)11 cited
• → THE CONFORMATION OF STERICALLY CONGESTED EIGHT-MEMBERED RINGS CONTAINING GERMANIUM: FIRST X-RAY CRYSTALLOGRAPHIC CHARACTERIZATION OF THE BOAT CONFORMATION(2004)7 cited
• → Facile Phosphite to Phosphonate Rearrangement of a Trialkanolamine-derived Triphosphite Promoted by Triethylaluminum(2007)1 cited