Jesús M. Fernández

Publications by Year

Research Areas

Asymmetric Hydrogenation and Catalysis, Asymmetric Synthesis and Catalysis, Chemical Synthesis and Analysis, Inorganic and Organometallic Chemistry, Organometallic Complex Synthesis and Catalysis

Most-Cited Works

• → Synthetic approaches to the chiral, pyramidal, transition-metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+X-. Generation, characterization, and reactions of a dichloromethane adduct(1989)78 cited
• → Selective binding and activation of one aldehyde enantioface by a chiral transition-metal Lewis acid: synthesis, structure, and reactivity of rhenium aldehyde complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-O:CHR)]+X-(1990)63 cited
• → Cleavage of the rhenium-methyl bond of (.eta.-C5H5)Re(NO)(PPh3)(CH3) by protic and halogen electrophiles: stereochemistry at rhenium(1984)61 cited
• → Selective activation of one methyl ketone enantioface via .sigma.-binding to a chiral transition-metal template: synthesis, structure, and reactivity of rhenium ketone complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.1-O:C(CH3)R)]+X-(1990)57 cited
• → Cyclopentadienyl Rhenium Complexes(1992)55 cited
• → Generation and reactions of chiral, pyramidal, transition-metal Lewis acids, .eta.5-cyclopentadienylnitrosyl(triphenylphosphine)rhenium(1+) complexes(1986)44 cited
• → A new asymmetric synthesis of cyanohydrins and oxygen-functionalized derivatives: stereoselective addition of cyanide to chiral rhenium aldehyde and ketone complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(O:CRR')]+BF4-(1991)40 cited
• → Synthesis, structure, and reactivity of the formaldehyde complex [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-H2C:O)]+ PF6-(1986)38 cited
• → A general method for the selective binding and activation of one aldehyde enantioface. Synthesis and reactivity of rhenium aldehyde complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-RCHO)]+ PF6-(1986)32 cited
• → Selective binding of one enantioface of monosubstituted alkenes to the chiral transition metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+(1988)20 cited