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Casper H. Stam

Analytisches Laboratorium(DE)Vrije Universiteit Amsterdam(NL)University of Amsterdam(NL)

Publications by Year

Research Areas

Organometallic Complex Synthesis and Catalysis, Metal complexes synthesis and properties, Asymmetric Hydrogenation and Catalysis, Coordination Chemistry and Organometallics, Ferrocene Chemistry and Applications

Most-Cited Works

→ New neutral and ionic methyl and chloro palladium and platinum complexes containing hemilabile phosphorus-nitrogen ligands. Study of the insertion of carbon monoxide into the metal-methyl bond(1992)195 cited
→ Intramolecularly chelated di- and tetranuclear aryllithium compounds: crystal structure of Li4[C6H4(2-CH2NMe2)]4 containing 4-center 2-electron-bonded C(aryl) atoms and heptacoordinate lithium atoms(1982)140 cited
→ Oxidative addition - reductive elimination reactions of mono- and bis(aryl)platinum(II) complexes with two amino ligands in fixed trans positions. X-ray crystal structures of (2,6-bis[[dimethylamino]methyl]phenyl)(4-tolyl)platinum(IV) diiodide and (2,6-bis[[dimethylamino]methyl]phenyl)platinum(IV) trichloride(1990)74 cited
→ Synthesis and structure of pentacarbonyl(mesityldiphenylmethylenephosphine)-chromium(0)(1981)72 cited
→ Syntheses and structural aspects of rigid aryl- palladium(II) and -platinum(II) complexes. X-ray crystal structure of o,o′-bis[(dimethylamino)methyl]phenyl- platinum(II) bromide(1986)67 cited
→

Arylnickel(III) species containing nitrogen trioxide, nitrogen dioxide, and thiocyanate ligands. ESR data and the x-ray crystal structure of hexacoordinate (pyridine)bis(thiocyanato)[o,o'-bis{(dimethylamino)methyl}phenyl]nickel(III)

(1986)

58 cited

→ Reactivity of cycopalladated compounds. 14. Alkyne insertion into the palladium-carbon bond of a metallacycle stabilized by a weak oxygen .fwdarw. palladium bond leading to an unusual (.eta.2-aryl) .fwdarw. palladium interaction molecular structure of [NC9H6CH2C(CF3):C(CF3)]Pd[C(CF3):C(CF3)(.eta.2-C10H6)OCH3](1987)55 cited

→ Reversible binding of sulfur dioxide to arylplatinum(II) and nickel(II) complexes. X-ray crystal structure of the five-coordinate platinum(II)-sulfur dioxide complex [PtBr(C6H3(CH2NMe2)2-o,o')(.eta.1-SO2)](1986)52 cited

→ Reactions of bis(iminophosphoranyl)methanes with chloro-bridged rhodium or iridium dimers giving complexes in which the ligand is coordinated either as a σ-N,σ-N′ or as a σ-N, σ-C chelate. X-ray crystal structure of the σ-N, σ-N′ Rh(I) complex Rh{(4-CH3-C6H4-NPPh2)2CH2}(COD)]PF6(1991)49 cited

→ Synthesis of trans-(.sigma.-allenyl)platinum(II) and -palladium(II) compounds. X-ray crystal structure of trans-[PtBr{C(H):C:CMe2}(PPh3)2] and highly diastereoselective trans-cis isomerization of (.sigma.-allenyl)palladium(II) bromides(1994)48 cited