Formation of an Aqueous Oxoiron(IV) Complex at pH 2–6 from a Nonheme Iron(II) Complex and H2O2
Citations Over TimeTop 10% of 2006 papers
Abstract
A ferryl cation in water: Iron(II) coordinated by the pentadentate ligand L reacts with H2O2 to form a low-spin FeIVO complex with S=1 (2 in scheme) under conditions similar to those of the classical Fenton reaction. Complex 2 differs from a recently obtained high-spin aquated oxoiron(IV) species and demonstrates the role of the supporting polydentate ligand in controlling spin state and product formation. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z601134_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Related Papers
- → Synthesis, characterization and reactivity of ionic palladium(II) complexes containing bidentate nitrogen ligands in a unidentate coordination mode,(1999)28 cited
- → Notes. Ligand additivity in the oxidation potentials of bidentate mixed-ligand ruthenium(II) complexes(1989)23 cited
- → The multidentate chemistry of manganese(II). II. Six and eight coordinate compounds with bidentate ligands(1973)18 cited
- → Aspects of the Stereochemistry of Seven‐Coordination(1979)72 cited
- → The mixed ligand [2+1] approach: An easier way of labeling the [M(CO)3]+ core (M=99,99MTC, RE)?(2001)1 cited