Na2Li8[(UO2)11O12(WO5)2]: Three Different Uranyl‐Ion Coordination Geometries and Cation–Cation Interactions
Angewandte Chemie International Edition2006Vol. 45(43), pp. 7233–7235
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Evgeny V. Alekseev, Sergey V. Krivovichev, Wulf Depmeier, Oleg I. Siidra, Karsten Knorr, Е. В. Сулейманов, Е. В. Чупрунов
Abstract
Uranyl interactions: The title compound is the first example of an actinide compound that contains three different actinyl-ion coordination geometries, namely, octahedral, pentagonal bipyramidal, and hexagonal bipyramidal. Strong cation–cation interactions between the uranyl ions lead to pentamers with a rather unusual configuration (see picture; U dark gray, O light gray).
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