Selective Metal‐Catalyzed Transfer of H2 and CO from Polyols to Alkenes
ChemSusChem2013Vol. 6(3), pp. 426–429
Citations Over TimeTop 16% of 2013 papers
Abstract
Transmission of alcohols achieved: A method for the direct transfer of the CHOH function from simple polyols to alkenes has been developed. In a dual-reactor system, successive iridium-catalyzed dehydrogenations and decarbonylations of polyols such as glycerol and sorbitol generates a low pressure of syngas, which is directly used in ex situ alkene hydroformylation.
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