Stereochemical studies by molecular palpation
Journal of Physical Organic Chemistry2004Vol. 17(9), pp. 787–792
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Abstract
Abstract The conformational equilibrium of cyclohexanol was investigated by 129 Xe NMR spectroscopy. While the classical NMR approach focuses on a carbon or proton atom belonging to the molecule under investigation, in our 129 Xe NMR methodology we use the xenon atom as an external spy. Xenon is able to monitor the interconversion between the axial and the equatorial isomers of cyclohexanol. The conformational equilibrium constant was estimated and is in excellent agreement with the values obtained by 1 H and 13 C NMR. Copyright © 2004 John Wiley & Sons, Ltd.
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