Synthesis of Ru(II) Complexes of N-Heterocyclic Carbenes and Their Promising Photoluminescence Properties in Water
Inorganic Chemistry2004Vol. 43(22), pp. 6896–6898
Citations Over TimeTop 10% of 2004 papers
Seung Uk Son, Kang Hyun Park, Young-Shin Lee, Bo Yun Kim, Cheol Ho Choi, Myoung Soo Lah, Yun Hee Jang, Du‐Jeon Jang, Young Keun Chung
Abstract
Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)(3)(2+) and Ru(terpy)(2)(2+), respectively, were synthesized. The complex, which is analogous to Ru(terpy)(2)(2+), exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were carried out.
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