Enantiopure 1,1‘-Binaphthyl-Based Polyoxometalate-Containing Molecular Hybrids
Inorganic Chemistry2005Vol. 44(22), pp. 7711–7713
Citations Over TimeTop 16% of 2005 papers
Abstract
The first chiral molecular hybrids based on covalently linked polyoxometalate clusters and enantiopure 1,1'-binaphthyl units have been prepared. Their structures have been confirmed by (1)H NMR, FTIR, and ESI-MS measurements. Such hybrids show moderate chiroptical behavior in solutions, and Cotton effects are observed up to 450 nm, indicating chiral extension from the binaphthyl core to the cluster-containing pi-conjugated arms.
Related Papers
- → Synthesis of Enantiopure γ‐Lactones via a RuPHOX‐Ru Catalyzed Asymmetric Hydrogenation of γ‐Keto Acids(2018)26 cited
- → Synthesis of Enantiopure 5-Substituted 2,3-Methanopyrrolidines by Cyclization of Enantiopure α-Branched α-N-Homoallylamino Nitriles(2012)8 cited
- → A Valuable Synthetic Route to the Enantiopure Functionalized N‐Substituted Aziridines(2004)1 cited
- → ChemInform Abstract: Efficacious and Rapid Metal‐ and Solvent‐Free Synthesis of Enantiopure Oxazolines.(2015)
- → ChemInform Abstract: Chiral Pyridin‐3‐ones and Pyridines: Syntheses of Enantiopure 2,4‐Disubstituted 6‐Hydroxy‐1,6‐dihydro‐2H‐pyridin‐3‐ones, 2,3‐Disubstituted 4‐Iodopyridines, and Enantiopure 2,3‐Disubstituted 4‐Pyridinemethanols.(2012)