An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2‘-bithiazoline)(N3)2]n
Journal of the American Chemical Society2003Vol. 125(46), pp. 13976–13977
Citations Over TimeTop 1% of 2003 papers
Abstract
A novel end-on azide-bridged homospin 1D chain, Co(bt)(N3)2 (1) (bt = 2,2'-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5-6 K, typical of single-chain magnet behavior.
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