Kinetic Resolutions of Indolines by a Nonenzymatic Acylation Catalyst
Journal of the American Chemical Society2006Vol. 128(44), pp. 14264–14265
Citations Over TimeTop 10% of 2006 papers
Abstract
The first method for the kinetic resolution of indolines through catalytic N-acylation is described. To improve the selectivity factor, new planar-chiral PPY-derived catalysts were synthesized, wherein the chiral environment was systematically modified. This work provides a rare example of a nonenzyme-based acylation catalyst for the kinetic resolution of amines.
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