Spin Transition Charted in a Fluorophore-Tagged Thermochromic Dinuclear Iron(II) Complex
Journal of the American Chemical Society2011Vol. 133(40), pp. 15850–15853
Citations Over TimeTop 10% of 2011 papers
Yann Garcia, François Robert, Anil D. Naik, Guangyuan Zhou, Bernard Tinant, Koen Robeyns, Sébastien Michotte, Luc Piraux
Abstract
The first crystal structures of a dinuclear iron(II) complex with three N1,N2-1,2,4-triazole bridges in the high-spin and low-spin states are reported. Its sharp spin transition, which was probed using X-ray, calorimetric, magnetic, and (57)Fe Mossbauer analyses, is also delineated in the crystalline state by variable-temperature fluorimetry for the first time.
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