Chiral Counteranion-Aided Asymmetric Hydrogenation of Acyclic Imines
Journal of the American Chemical Society2008Vol. 130(44), pp. 14450–14451
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Abstract
When combined with a chiral phosphate counteranion, a chiral diamine-ligated Ir(III) catalyst displayed excellent enantioselectivities in the asymmetric hydrogenation of a wide range of acyclic imines, affording chiral amines in up to 99% ee.
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