Metal-Free Oxidative Cross-Coupling of Unfunctionalized Aromatic Compounds
Journal of the American Chemical Society2009Vol. 131(5), pp. 1668–1669
Citations Over TimeTop 1% of 2009 papers
Abstract
A new strategy for mixed biaryl synthesis has been developed using the hypervalent iodine(III) reagents. The unique reactivities of the sigma-heteroaryl iodine(III) intermediates generated in situ are the key element for the unusual metal catalyst-free transformations and strict control of the product selectivities.
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