Thermal Effects of Water Intrusion in Hydrophobic Nanoporous Materials
Journal of the American Chemical Society2009Vol. 131(29), pp. 9898–9899
Citations Over TimeTop 20% of 2009 papers
Abstract
Liquid water intrusion in hydrophobic nanoporous silicalite-1, a pure siliceous zeolite, in isothermal conditions under high pressure produces an endothermic effect. After intrusion, confined water in zeolite pores is in a different state from that of the liquid bulk water. Such forced intrusion also chemically modifies the material and tends to render it slightly more hydrophilic.
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