Highly Enantioselective Approach to Indolizidines: Preparation of (+)-(1S,8aS)-1-Hydroxyindolizidine and (−)-Slaframine
The Journal of Organic Chemistry2000Vol. 65(21), pp. 6966–6972
Citations Over TimeTop 10% of 2000 papers
Abstract
A highly stereoselective approach to (-)-slaframine and its probable biosynthetic precursor (+)-(1S,8aS)-1-hydroxyindolizidine has been developed based on a diastereofacially selective cycloaddition of dichloroketene with a chiral dienol ether.
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