Zn(II)-Catalyzed Thiolysis of Oxiranes in Water under Neutral Conditions
The Journal of Organic Chemistry2003Vol. 68(21), pp. 8248–8251
Citations Over TimeTop 10% of 2003 papers
Abstract
Thiolysis of a variety of 1,2-epoxides in water at 30 degrees C and pH 7.0 is strongly accelerated by ZnCl(2) (10 mol %) except when amino- and carboxythiophenol are used. The aqueous medium and the catalyst were recovered and reused in various runs without affecting the efficiency of the process.
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