Preparation of NHC Borane Complexes by Lewis Base Exchange with Amine− and Phosphine−Boranes
The Journal of Organic Chemistry2010Vol. 75(20), pp. 6983–6985
Citations Over TimeTop 11% of 2010 papers
Malika Makhlouf Brahmi, Julien Monot, Marine Desage‐El Murr, Dennis P. Curran, Louis Fensterbank, Emmanuel Lacôte, Max Malacrìa
Abstract
A versatile new method for the preparation of NHC boranes starting from two stable, readily available reactants-an heterocyclic salt and an amine or phosphine-borane-is reported. It uses a Lewis base exchange at boron and provides easy access to new NHC boranes, in particular B-substituted borane ones.
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