IMDAF/Aromatization Path of Halogenated Furylacrylamides and Furylpropiolamides to Dihydroisoquinolin-1(2H)-ones
The Journal of Organic Chemistry2013Vol. 78(6), pp. 2564–2570
Citations Over TimeTop 14% of 2013 papers
Abstract
Intramolecular Diels-Alder cycloadditions of chlorofuryl- (R = Cl) secondary (R' = H) acrylamides and propiolamides of type 1 followed by (optional modification and) base-induced aromatization of the resulting chlorinated oxanorborn(adi)enes 2 afford N-free-dihydroisoquinolin-1(2H)-ones 3 with different aromatic substitution patterns.
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