Fundamental Strategy for Creating VLS Grown TiO₂ Single Crystalline Nanowires

Citations Over TimeTop 22% of 2012 papers

Abstract

A single crystalline TiO2 nanowire grown by a size and position controllable vapor–liquid–solid (VLS) method is a promising candidate to control and design the physical and chemical properties for various TiO2-based applications. However, creating TiO2 nanowires by VLS has been a challenging issue due to a difficulty on controlling and understanding the complex material transport events across three phases. Here we propose a fundamental strategy to create a TiO2 single crystalline nanowire by the VLS mechanism. We show that a VLS growth of TiO2 nanowires can emerge intrinsically only within a quite narrow range of material flux, which is a sharp contrast to typical VLS oxides including MgO, SnO2, In2O3, and ZnO, whose nanowires are easily grown by VLS with much wider ranges of material flux. We reveal that a condensation of Ti atoms at a vapor–solid interface, which is detrimental for VLS, is responsible to limit a window of material flux for TiO2 nanowires. In addition, we found that our rutile-TiO2 nanowires preferentially grow along ⟨001⟩ direction, which interestingly differs from a typical ⟨110⟩ oriented growth of TiO2 nanowires formed by the vapor-phase method. The present approach based on a control of material flux provides a foundation to tailor VLS grown TiO2 nanowires based on a scientific strategy rather than a rule of thumb.

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