Enantioselective Synthesis of (−)-Dendroprimine and Isomers
Journal of Natural Products2004Vol. 67(6), pp. 1029–1031
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Abstract
An enantioselective and diastereoselective synthesis of six 5,7-dimethylindolizidine isomers is described via an intramolecular cyclization that involves an allylsilyl nucleophilic group and an acyliminium ion. The first total synthesis of naturally occurring (-)-dendroprimine has been achieved in five steps.
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