Asymmetric Synthesis of Quaternary α-Amino Phosphonates Using Sulfinimines
Organic Letters2001Vol. 3(11), pp. 1757–1760
Citations Over TimeTop 15% of 2001 papers
Abstract
The addition of lithium diethylphosphonate to enantiopure ketosulfinimines is highly diastereoselective (>95%), affording the first examples of quaternary alpha-alkyl alpha-amino (arylmethyl)phosphonates.
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