A Divergent Approach to the Myriaporones and Tedanolide: Completion of the Carbon Skeleton of Myriaporone 1
Organic Letters2002Vol. 4(17), pp. 2953–2955
Citations Over TimeTop 11% of 2002 papers
Abstract
[reaction: see text] A linear but concise synthetic approach toward the structurally related natural products myriaporone and tedanolide is reported. The route is highlighted by a stereoselective homoallenylboration and a regio- and chemoselective nitrile oxide cycloaddition. Installation of the (Z)-olefin completed the carbon skeleton of myriaporone 1.
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