Efficient Copper-Mediated Reactions of Nitrenes Derived from Sulfonimidamides
Organic Letters2004Vol. 6(20), pp. 3573–3575
Citations Over TimeTop 10% of 2004 papers
Abstract
[reaction: see text] Sulfonimidamides lead efficiently to nitrenes and have been converted to sulfimides, sulfoximines, and aziridines in good yields, through a copper-mediated multicomponent reaction. The stereogenic sulfur atom and the trivalent nitrogen atom present in the molecules open the way to asymmetric synthesis, whose first results are presented.
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