Remarkable Structure Deformation in Phenothiazine Trimer Radical Cation
Organic Letters2004Vol. 6(20), pp. 3493–3496
Citations Over TimeTop 23% of 2004 papers
Toshihiro Okamoto, M. Kuratsu, Masatoshi Kozaki, Ken Hirotsu, Akio Ichimura, Toshio Matsushita, Keiji Okada
Abstract
[structure: see text] A trimeric phenothiazine and its radical cation were prepared, and their structures were elucidated. In contrast to a largely twisted structure in the neutral species, the radical cation had a unique structure deformation that allowed charge-transfer-type conjugation from the outer phenothiazine rings to the central phenothiazine radical cation.
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