Synthesis and Characterization of 5-Octylthieno[3,4-c]pyrrole-4,6-dione Derivatives As New Monomers for Conjugated Copolymers
Organic Letters2010Vol. 13(1), pp. 38–41
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Philippe Berrouard, François Grenier, Jean‐Rémi Pouliot, Éric Gagnon, Christian Tessier, Mario Leclerc
Abstract
An efficient route for the synthesis of 1-iodo-5-octyl-4H-thieno[3,4-c]pyrrole-4,6(5H)-dione as a key intermediate to build new electron-deficient monomers and related conjugated polymers is reported. Along these lines, two new low bandgap copolymers were synthesized from Stille or Suzuki coupling. These polymers were characterized and their properties compared to those of analogous conjugated polymers.
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