Synthesis of the Asperparaline Core by a Radical Cascade
Organic Letters2011Vol. 13(24), pp. 6472–6475
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Abstract
A concise access to the pentacyclic core structure of the asperparalines is described. The key step is a radical cascade sequence comprised of a 1,6-hydrogen atom transfer followed by 6-exo-trig and 5-exo-trig cyclizations.
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