Thioether-Promoted Direct Olefination of Polyfluoroarenes Catalyzed by Palladium
Organic Letters2013Vol. 15(20), pp. 5266–5269
Citations Over TimeTop 10% of 2013 papers
Abstract
A methyl(phenyl)sulfane-promoted direct olefination of polyfluoroarenes catalyzed by palladium has been reported. With use of this new thioether ligand, a high reaction efficiency and excellent E/Z ratio of desired olefinated polyfluoroarenes were obtained. This represents a first example of thioether promoted oxidative Heck reaction.
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