A Zwitterionic Palladium(II) η3-Boratoxypentadienyl Complex: Cooperative Activation of Dibenzylideneacetone between Palladium and a Phosphine/Thioether/Borane Ligand
Organometallics2006Vol. 25(10), pp. 2412–2414
Citations Over TimeTop 10% of 2006 papers
Abstract
A free phosphine/thioether/borane ligand (5) suitable to position a Lewis acidic borane in close proximity to a coordinated late transition metal has been prepared. Reaction with 0.5 [Pd2(dba)3] gave a zwitterionic palladium(II) η3-boratoxypentadienyl complex with the empirical formula [Pd(dba)(5)].
Related Papers
- → A Zwitterionic Palladium(II) η3-Boratoxypentadienyl Complex: Cooperative Activation of Dibenzylideneacetone between Palladium and a Phosphine/Thioether/Borane Ligand(2006)53 cited
- → Palladium and platinum complexes with planar chiral 1,2-disubstituted ferrocenes containing phosphine and thioether donor groups(2007)19 cited
- → Bis(pentachlorophenyl) derivatives of palladium(II)(1977)18 cited
- → Polypyrrole bearing diphosphine borane groups: a new way to prepare polymer-supported phosphine ligands. Application to palladium catalysed reactions(1997)13 cited
- Coordination of Phosphine-Thioether Ligands to Low-valent Metal Centers(2009)