Cross-Coupling Hydrogen Evolution Reaction in Homogeneous Solution without Noble Metals
Organic Letters2014Vol. 16(7), pp. 1988–1991
Citations Over TimeTop 10% of 2014 papers
Jian‐Ji Zhong, Qingyuan Meng, Bin Liu, Xu‐Bing Li, Xue‐Wang Gao, Tao Lei, Chengjuan Wu, Zhijun Li, Chen‐Ho Tung, Li‐Zhu Wu
Abstract
A highly efficient noble-metal-free homogeneous system for a cross-coupling hydrogen evolution (CCHE) reaction is developed. With cheap, earth-abundant eosin Y and molecular catalyst Co(dmgH)2Cl2, good to excellent yields for coupling reactions with a variety of isoquinolines and indole substrates and H2 have been achieved without any sacrificial oxidants. Mechanistic insights provide rich information on the effective, clean, and economic CCHE reaction.
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