Synthesis of Fluoroalkyl Palladium and Nickel Complexes via Decarbonylation of Acylmetal Species
Organometallics2014Vol. 33(14), pp. 3831–3839
Citations Over TimeTop 18% of 2014 papers
Abstract
The synthesis and characterization of a series of fluoroalkyl palladium(II) and nickel(II) complexes via decarbonylation of the corresponding acylmetal species is reported. At palladium(II), labile supporting ligands such as tri-o-tolylphosphine are required to achieve decarbonylation within 30 min at 85 °C. In contrast, decarbonylation at (PPh3)2Ni(C(O)RF)(OCORF) (RF = fluoroalkyl) complexes proceeds rapidly at or below room temperature.
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